Blair is in for a few big surprises on her first day at Columbia; Serena becomes suspicious of Juliet (Katie Cassidy); worried about Dan, Rufus decides to take matters into his own hands.
Lily asks Serena to help her find Chuck; Juliet offers to help Nate win Serena back.
Nate decides to confront Juliet when he thinks she is keeping a secret from him; Blair tries to undermine Chuck's newfound happiness; Dan is torn between his feelings for Serena and Vanessa.
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